全文获取类型
收费全文 | 303篇 |
免费 | 7篇 |
国内免费 | 2篇 |
专业分类
化学 | 188篇 |
晶体学 | 8篇 |
力学 | 5篇 |
数学 | 23篇 |
物理学 | 88篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 7篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 7篇 |
2013年 | 15篇 |
2012年 | 9篇 |
2011年 | 16篇 |
2010年 | 12篇 |
2009年 | 14篇 |
2008年 | 29篇 |
2007年 | 23篇 |
2006年 | 23篇 |
2005年 | 12篇 |
2004年 | 13篇 |
2003年 | 14篇 |
2002年 | 16篇 |
2001年 | 9篇 |
2000年 | 3篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1968年 | 1篇 |
1942年 | 2篇 |
排序方式: 共有312条查询结果,搜索用时 437 毫秒
11.
Atsushi Sudo Tomoki Yamasaki Takuro Yamashita Dai Ishida 《Journal of polymer science. Part A, Polymer chemistry》2019,57(24):2407-2414
Oligo(spiroketal)s (OSKs) were synthesized from myo‐inositol, a naturally occurring cyclic compound bearing six hydroxyl groups. The successful synthesis of OSKs was achieved using silyl ethers 2 derived from 1,4‐di‐O‐alkylated myo‐inositol 1 as monomers, which underwent polycondensation with 1,4‐cyclohexanedione (CHD) at 0 °C in the presence of trimethylsilyl triflate as a catalyst. Because of the irreversible nature of the condensation reaction of silyl ethers with ketones, the resulting OSKs 7 had higher molecular weights than previously reported OSKs that were obtained by polycondensation of tetraols 1 with CHD, where backward hydrolysis of the ketal functions occurred. In addition, another series of OSKs, 8, were synthesized using silyl ethers 3 derived from 2,5‐di‐O‐alkylated myo‐inositol 6 , which are more symmetric monomers than silyl ethers 2 . Silyl ethers 3 underwent efficient polycondensation with CHD, whereas tetraol 6 did not, demonstrating that the derivation of such tetraols into the corresponding silyl ethers is a powerful strategy to access OSKs. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 2407–2414 相似文献
12.
Kun'ichi Miyazawa Takuro Nagai Koji Kimoto Masaru Yoshitake Yumi Tanaka 《Surface and interface analysis : SIA》2021,53(1):84-89
We analyzed the surface atomic structure of highly oriented pyrolytic graphite (HOPG) substrate exfoliated with adhesive tape, using high‐resolution transmission electron microscopy and scanning transmission electron microscopy‐electron energy‐loss spectroscopy (STEM‐EELS). The surface step height of the exfoliated HOPG substrate was determined using high‐angle annular dark‐field‐scanning transmission electron microscopy (HAADF‐STEM) images and the depth profiles of the EELS spectra of a cross‐sectioned thin foil specimen prepared via focused ion beam milling. The exfoliated surface of the HOPG substrate presented disordered and curved graphene layers. The STEM‐EELS measurements indicated that upon exfoliation, the surface of the HOPG substrate reacted with atmospheric water and oxygen molecules. 相似文献
13.
Shuichi Ebisawa Takuro Tsutsumi Tetsuya Taketsugu 《Journal of computational chemistry》2021,42(1):27-39
A mathematical aspect of the anharmonic downward distortion following (ADDF) path is discussed. The ADDF method is utilized as an automated reaction path search method, which can explore transition state geometries on a potential energy surface from a potential minimum. We show that the maximum number of the ADD stationary paths intersecting the potential minimum is 2f + 1 ? 2 , where f denotes the degree of freedom of the system. We also show that the bifurcation of the ADD stationary path is essential to detect all the transition states connected from a given minimum. The ADDF computation is demonstrated for a H2O molecule in which pitchfork bifurcation is observed. 相似文献
14.
15.
Julien Labaune J. Bianca Jackson Kaori Fukunaga Jeffrey White Laura d’Alessandro Alison Whyte Michel Menu Gerard Mourou 《Applied Physics A: Materials Science & Processing》2011,105(1):5-9
Terahertz Time Domain Imaging has been used in the last few years for the investigation of cultural heritage. In this article,
the authors demonstrate the possibility to apply it for the investigation of clay artifacts. Tomographic images were obtained
of a model in reflection, and an Egyptian vessel in transmission. 相似文献
16.
Krokovny P Abe K Abe K Abe T Adachi I Ahn BS Aihara H Akatsu M Asano Y Aso T Aulchenko V Aushev T Bakich AM Ban Y Banas E Bay A Bedny I Behera PK Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Danilov M Dong LY Drutskoy A Eidelman S Eiges V Enari Y Everton CW Fang F Fukunaga C Gabyshev N Garmash A Gershon T Golob B Gordon A Guo R Haba J Hanagaki K Handa F Harada Y Hayashii H Hazumi M Heenan EM Higuchi T Hinz L Hojo T 《Physical review letters》2002,89(23):231804
We report the first observation of a B meson decay that is not accessible by a direct spectator process. The channel B(0)-->D(+)(s)K- is found in a sample of 85 x 10(6) BB; events, collected with the Belle detector at KEKB, with a branching fraction B(B(0)-->D(+)(s)K-)=(4.6(+1.2)(-1.1)+/-1.3) x 10(-5). We also obtain evidence for the B0-->D(+)(s)pi(-) decay with branching fraction B(B0-->D(+)(s)pi(-))=(2.4(+1.0)(-0.8)+/-0.7) x 10(-5). This value may be used to extract a model-dependent value of |V(ub)|. 相似文献
17.
18.
Fang F Hojo T Abe K Abe K Abe T Adachi I Aihara H Akatsu M Asano Y Aso T Aulchenko V Bakich AM Ban Y Banas E Bay A Behera PK Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Choi YK Danilov M Drutskoy A Eidelman S Eiges V Enari Y Fukunaga C Gabyshev N Garmash A Gershon T Golob B Hara T Hastings NC Hayashii H Hazumi M Heenan EM Higuchi T Hinz L Hokuue T Hoshi Y Hou WS Huang HC Igaki T Igarashi Y Iijima T Inami K 《Physical review letters》2003,90(7):071801
We report measurements of branching fractions for charged and neutral B-->eta(c)K decays where the eta(c) meson is reconstructed in the K(0)(S)K+/-pi(-/+), K+K-pi(0), K(*0)K-pi(+), and pp; decay channels. The neutral B0 channel is a CP eigenstate and can be used to measure the CP violation parameter sin(2phi(1). We also report the first observation of the B0-->eta(c)K(*0) mode. The results are based on an analysis of 29.1 fb(-1) of data collected by the Belle detector at KEKB. 相似文献
19.
Abe K Abe K Adachi I Ahn BS Aihara H Akatsu M Alimonti G Aoki K Asai K Asai M Asano Y Aso T Aulchenko V Aushev T Bakich AM Banas E Behari S Behera PK Beiline D Bondar A Bozek A Browder TE Casey BC Chang P Chao Y Cheon BG Choi SK Choi Y Doi Y Dragic J Eidelman S Enari Y Enomoto R Everton CW Fang F Fujii H Fujita Y Fukunaga C Fukushima M Garmash A Gordon A Gotow K Guler H Guo R Haba J Haji T Hamasaki H Hanagaki K Handa F Hara K Hara T Hastings NC Hayashi K Hayashii H Hazumi M Heenan EM Higuchi I 《Physical review letters》2001,86(15):3228-3232
We report a determination of the B(0)(d)-&B_(0)(d) mixing parameter Deltam(d) based on the time evolution of dilepton yields in Upsilon(4S) decays. The measurement is based on a 5.9 fb(-1) data sample collected by the Belle detector at KEKB. The proper-time difference distributions for same-sign and opposite-sign dilepton events are simultaneously fitted to an expression containing Deltam(d) as a free parameter. Using both muons and electrons, we obtain Deltam(d) = 0.463+/-0.008 (stat)+/-0.016 (syst) ps(-1). This is the first determination of Deltam(d) from time evolution measurements at the Upsilon(4S). We also place limits on possible CPT violations. 相似文献
20.
Abe K Abe K Abe R Adachi I Ahn BS Aihara H Akatsu M Alimonti G Asai K Asai M Asano Y Aso T Aulchenko V Aushev T Bakich AM Banas E Behari S Behera PK Beiline D Bondar A Bozek A Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Dong LY Dragic J Drutskoy A Eidelman S Eiges V Enari Y Enomoto R Everton CW Fang F Fujii H Fukunaga C Fukushima M Gabyshev N Garmash A Gershon TJ Gordon A Gotow K Guler H Guo R Haba J Hamasaki H Hanagaki K Handa F Hara K Hara T Hastings NC 《Physical review letters》2001,87(9):091802
We present a measurement of the standard model CP violation parameter sin2 phi(1) based on a 29.1 fb(-1) data sample collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. One neutral B meson is fully reconstructed as a J/psi K(S), psi(2S)K(S), chi(c1)K(S), eta(c)K(S), J/psi K(L), or J/psi K(*0) decay and the flavor of the accompanying B meson is identified from its decay products. From the asymmetry in the distribution of the time intervals between the two B meson decay points, we determine sin2 phi(1) = 0.99+/-0.14(stat)+/-0.06(syst). We conclude that we have observed CP violation in the neutral B meson system. 相似文献